Cobalt(III)-Catalyzed Directed C-H Coupling with Diazo Compounds: Straightforward Access towards Extended π-Systems

Zhao, D.; Kim, J. H.; Stegemann, L.; Strassert, C. A.; Glorius, F.

Research article (journal) | Peer reviewed

Abstract

Abstract The first highly efficient and scalable cobalt-catalyzed directed CH functionalization with carbene precursors is presented. This methodology provides a modular route towards a new class of conjugated polycyclic hydrocarbons with tunable emission wavelengths both in solution and in the solid state.

Details about the publication

JournalAngewandte Chemie International Edition (Angew. Chem. Int. Ed.)
Volume54
Issue15
Page range4508-4511
StatusPublished
Release year2015
Language in which the publication is writtenEnglish
DOI10.1002/anie.201411994
Link to the full texthttps://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201411994
Keywordscarbenes; CH activation; cobalt; heterocycles; π-systems

Authors from the University of Münster

Glorius, Frank
Professur für Organische Chemie (Prof. Glorius)
Strassert, Cristian
Professoship for Coordination Chemistry and Functional Imaging