Oxygen-insensitive phosphorescence in water from a Pt-doped supramolecular array

Straub, L.; González-Abradelo, D.; Strassert, C. A.

Research article (journal) | Peer reviewed

Abstract

A supramolecular array consisting of polyvinylpyridine decorated with adamantyl-substituted Pt(ii) complexes is described. Upon complexation of the adamantyl units with cyclodextrins{,} a transfer into the aqueous phase can be achieved leading to an oxygen-insensitive phosphorescence. The unique properties arise from a diffusional shielding of the emitters from the environment provided by the compact self-assembled array.

Details about the publication

JournalChemical communications (Chem. Commun.)
Volume53
Page range11806-11809
StatusPublished
Release year2017
Language in which the publication is writtenEnglish
DOI10.1039/C7CC05435A
Link to the full texthttp://dx.doi.org/10.1039/C7CC05435A
KeywordsPt(ii) complex; oxygen-insensitive

Authors from the University of Münster

Strassert, Cristian
Professoship for Coordination Chemistry and Functional Imaging