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RhIII-Catalyzed C-H Activation with Pyridotriazoles: Direct Access to Fluorophores for Metal-Ion Detection

Kim, J. H.; Gensch, T.; Zhao, D.; Stegemann, L.; Strassert, C. A.; Glorius, F.

Research article (journal) | Peer reviewed

Abstract

Abstract The first CH bond activation with pyridotriazoles as coupling partners is presented using a RhIII catalyst. The pyridotriazoles can be used as new carbene precursors in CH activation for direct access to novel fluorescent scaffolds. These tunable fluorophores can be applied for the detection of metal ions.

Details about the publication

Journal: Angewandte Chemie International Edition (Angew. Chem. Int. Ed.)
Volume: 54
Issue: 37
Page range: 10975-10979
Status: Published
Release year: 2015
Language in which the publication is written: English
DOI: 10.1002/anie.201504757
Link to the full text: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201504757
Keywords: carbene; CH activation; fluorophore; rhodium; triazole

Authors from the University of Münster

Glorius, Frank
Professur für Organische Chemie (Prof. Glorius)
Strassert, Cristian
Professoship for Coordination Chemistry and Functional Imaging