Self-assembly of molecular cylinders from polycarbene ligands and Ag(I) or Au(I).

Rit A., Pape T., Hahn F. E.

Research article (journal)

Abstract

Tris- and tetrakis(imidazolium) salts react with Ag(2)O to give cylindrical polynuclear silver(I) complexes such as the tetrasilver derivative [Ag(4)(1)(2)](PF(6))(4). The silver(I) complexes undergo transmetalation with [AuCl(SMe(2))] to yield homonuclear gold(I) complexes with retention of the metallosupramolecular assembly.

Details zur Publikation

Pages: -4568
Release year: 2010
Language in which the publication is written: Uncoded languages