Oxidizing Directing Groups Enable Efficient and Innovative C-H Activation Reactions
Patureau FW, Glorius F
Research article (journal)Abstract
The use of internal oxidants, embedded in the directing group, in C H activation reactions can lead to higher levels of selectivity and reactivity under milder conditions (see examples). An internal oxidant can be defined as a covalent bond within one of the coupling substrates which oxidizes the metal catalyst. This should open up new avenues in the field of C H activation.
Details about the publication
Journal: Angewandte Chemie International Edition (Angew. Chem. Int. Ed.)
Volume: 50
Issue: 9
Page range: 1977-1979
Status: Published
Release year: 2011 (31/12/2011)
Language in which the publication is written: English
Keywords: C-H activation cross-coupling oxidation sustainable chemistry carbon-hydrogen bonds silylation cleavage hydrosilanes amination arenes acids
Authors from the University of Münster
| Glorius, Frank | Professur für Organische Chemie (Prof. Glorius) |