Chiral olefin Ligands - New "Spectators" in asymmetric catalysis
Glorius F
Research article (journal)Abstract
such as 1 (shown with its catalytically active Rh complex 2) have been applied successfully in asymmetric catalysis recently. New coordination geometries are possible with this class of ligands, and the electronic character of the olefin ligand can be varied over a wide range, leading to catalysts with increased stability, selectivity, and catalytic activity.
Details about the publication
Journal: Angewandte Chemie International Edition (Angew. Chem. Int. Ed.)
Volume: 43
Issue: 26
Page range: 3364-3366
Status: Published
Release year: 2004 (31/12/2004)
Language in which the publication is written: English
Keywords: alkene ligands asymmetric catalysis homogeneous catalysis ligand design allylic alkylation 1,4-addition complexes mop coordination substitution carbonates esters acids cycle
Authors from the University of Münster
| Glorius, Frank | Professur für Organische Chemie (Prof. Glorius) |