The conductivity of pyrrolidinium and sulfonylimide-based ionic liquids: A combined experimental and computational study

Johansson P, Fast LE, Matic A, Appetecchi GB, Passerini S

Forschungsartikel (Zeitschrift)

Zusammenfassung

Ionic conductivity is a fundamental property of ionic liquids with its origin and exact nature under debate. Using a specially selected system of pyrrolidinium cations (PYR1x, x = 3,4) and sulfonylimide anions (FSI, TFSI, BETI, and IM14)-based ionic liquids we observe a simple and accurate connection between ab initio computed cation and anion volumes and measured molar ionic conductivities. (C) 2009 Elsevier B.V. All rights reserved.

Details zur Publikation

FachzeitschriftJournal of Power Sources
Jahrgang / Bandnr. / Volume195
Ausgabe / Heftnr. / Issue7
Seitenbereich2074-2076
StatusVeröffentlicht
Veröffentlichungsjahr2010 (02.04.2010)
Sprache, in der die Publikation verfasst istEnglisch
DOI10.1016/j.jpowsour.2009.10.029
StichwörterIonic liquid Lithium battery C3mpyr C4mpyr Conductivity Ab initio anions density tetrafluoroborate diffusion viscosity cation

Autor*innen der Universität Münster

Passerini, Stefano
Münster Electrochemical Energy Technology Battery Research Center (MEET)