A planar chiral [2.2]paracyclophane derived N-heterocyclic stannylene

Piel I, Dickschat JV, Pape T, Hahn FE, Glorius F

Research article (journal) | Peer reviewed

Abstract

The reaction of pseudo-ortho-4,12-N,N′-diphenyldiamino-[2.2] paracyclophane ((±)-3) with Sn[N(SiMe3)2] 2 results in the formation of the monomeric planar chiral N-heterocyclic stannylene (±)-4, featuring a unique [2.2]paracyclophane backbone, which has been characterized by an X-ray diffraction study. © 2012 The Royal Society of Chemistry.

Details about the publication

JournalDalton Transactions (Dalton Trans.)
Volume41
Issue45
Page range13788-13790
StatusPublished
Release year2012 (07/12/2012)
Language in which the publication is writtenEnglish
DOI10.1039/c2dt31497e

Authors from the University of Münster

Dickschat, Julia
Sonderforschungsbereich 858 - "Synergetische Effekte in der Chemie - Von der Additivität zur Kooperativität"
Glorius, Frank
Professur für Organische Chemie (Prof. Glorius)
Hahn, Franz Ekkehardt
Professorship of Inorganic Chemistry (Prof. Hahn)