[3]Dendralene synthesis: rhodium(III)-catalyzed alkenyl C-H activation and coupling reaction with allenyl carbinol carbonate.

Wang H, Beiring B, Yu DG, Collins KD, Glorius F

Abstract

[3]DendrAl(l)ene! A new synthesis of [3]dendralenes is based on a Rh(III) -catalyzed alkenyl CH activation and coupling reaction with allenyl carbinol carbonates (see scheme; DG=directing group). A variety of [3]dendralenes with diverse substitution patterns are accessible with good efficiency. The reaction is highly stereoselective and compatible with different directing groups and numerous functional groups.