Rhodium-Catalyzed Oxidative Olefination of C-H Bonds in Acetophenones and Benzamides
Patureau FW, Besset T, Glorius F
Research article (journal)Abstract
The metal-catalyzed oxidative C H functionalization of electron-rich arenes is well-established, but analogous reactions of electron-poor substrates are rare. A new application makes use of common electron-withdrawing functional groups (COMe, CONH2, CONEt2) in the rhodium-catalyzed oxidative Heck reaction to generate complex organic molecules. Cp*= η5-C5Me5.
Details about the publication
Journal: Angewandte Chemie International Edition (Angew. Chem. Int. Ed.)
Volume: 50
Issue: 5
Page range: 1064-1067
Status: Published
Release year: 2011 (31/12/2011)
Language in which the publication is written: English
Keywords: amination Heck reaction olefination rhodium stilbenes room-temperature pd(ii)-catalyzed olefination aromatic ketones direct arylation benzoic-acids aryl ketones activation functionalization alkynes indoles
Authors from the University of Münster
| Besset, Tatiana | Sonderforschungsbereich 858 - "Synergetische Effekte in der Chemie - Von der Additivität zur Kooperativität" |
| Glorius, Frank | Professur für Organische Chemie (Prof. Glorius) |