Investigation of the properties of 4,5-dialkylated N-heterocyclic carbenes
Urban S, Tursky M, Frohlich R, Glorius F
Research article (journal)Abstract
The investigation of the electronic and steric properties of 4,5-disubstituted imidazolylidenes is reported, as well as their successful application as organocatalysts in the formation of gamma-butyrolactones by conjugate Umpolung.
Details about the publication
Journal: Dalton Transactions (Dalton Trans.)
Issue: 35
Page range: 6934-6940
Status: Published
Release year: 2009 (31/12/2009)
Language in which the publication is written: English
DOI: 10.1039/b908981k
Keywords: cross-coupling reactions gamma-butyrolactones nucleophilic carbenes conjugate umpolung alpha; beta-unsaturated aldehydes homogeneous catalysis electronic-properties imidazolium salts stable carbenes ligands
Authors from the University of Münster
| Fröhlich, Roland | Organic Chemistry Institute |
| Glorius, Frank | Professur für Organische Chemie (Prof. Glorius) |
| Urban, Slawomir | Sonderforschungsbereich 858 - "Synergetische Effekte in der Chemie - Von der Additivität zur Kooperativität" |