Investigating organocatalytic reactions: mass spectrometric studies of a conjugate umpolung reaction

Schrader W, Handayani PP, Burstein C, Glorius F

Research article (journal)

Abstract

Anorganocatalyzed conjugate umpolung reaction has been studied in detail using electrospray mass spectrometry, which allows to support the catalytic cycle by intercepting intermediates.

Details about the publication

JournalChemical communications (Chem. Commun.)
Issue7
Page range716-718
StatusPublished
Release year2007 (31/12/2007)
Language in which the publication is writtenEnglish
DOI10.1039/b613862d
Keywordselectrospray-ionization mass carbene-catalyzed reaction n-heterocyclic carbenes stereoselective-synthesis gamma-butyrolactones alpha; beta-unsaturated aldehydes nucleophilic carbenes mechanism generation enals

Authors from the University of Münster

Glorius, Frank
Professur für Organische Chemie (Prof. Glorius)