Carbohydrate-containing n-heterocyclic carbene complexes
Tewes F, Schlecker A, Harms K, Glorius F
Forschungsartikel (Zeitschrift)Zusammenfassung
Novel carbohydrate bearing imidazolium salts have been synthesized and used for the in situ generation of the corresponding N-heterocyclic carbenes. These compounds were successfully used as catalysts of the conjugate umpolung of cinnamaldehyde to form gamma-butyrolactones. In addition, silver and palladium complexes of these N-heterocyclic carbenes were synthesized and structurally characterized. (C) 2007 Elsevier B.V. All rights reserved.
Details zur Publikation
Fachzeitschrift: Journal of Organometallic Chemistry
Jahrgang / Bandnr. / Volume: 692
Ausgabe / Heftnr. / Issue: 21
Seitenbereich: 4593-4602
Status: Veröffentlicht
Veröffentlichungsjahr: 2007 (01.10.2007)
Sprache, in der die Publikation verfasst ist: Englisch
Stichwörter: N-heterocyclic carbenes carbohydrates palladium complex silver complex catalysis asymmetric catalysis stereoselective-synthesis transesterification/acylation reactions gamma-butyrolactones alpha; beta-unsaturated aldehydes activated carboxylates nucleophilic carbenes living polymerization conjugate umpolung direct annulations
Autor*innen der Universität Münster
| Glorius, Frank | Professur für Organische Chemie (Prof. Glorius) |